RACEMIC DITHIOPHOSPHORIC ACIDS AND THEIR AMMONIMUM SALTS. SYNTHESIS AND MOLECULAR STRACTURE

Abstract: 

Racemic O,O-di(1-phenylethyl) dithiophosphoric acid was received by thiophosphorylation. This acid was transformed into ammonium salts by treatment of ammonia and (S)-(-)-1-phenylethylamine. The mo-lecular structure of D,L-1-phenylethylammonium salts of O,O-diethyl dithiophosphoric acid was estab-lished by single crystal X-ray analysis. 

Key words: 

thiophosphorylation, racemates, dithiophosphoric acids, X-ray analysis.

AttachmentSize
Cтатья (стр. 94-99)317.84 KB